Фотовольтаические свойства функционализированного индодикарбоцианинового красителя
DOI:
https://doi.org/10.31489/2022No3/55-59Ключевые слова:
полиметиновые красители, функциональные группы, оптические свойства, фотовольтаикаАннотация
Изучено влияние химического строения полиметиновых красителей на их спектрально-люминесцентные и фотовольтаические свойства. Показано, что введение функциональных групп в структуру красителя приводит к батохромному сдвигу полос поглощения и флуоресценции. При адсорбции красителей на поверхности диоксида титана был зарегистрирован сдвиг их спектров в область красных длин волн с одновременным уширением полос, вызванных агрегацией красителя на поверхности полупроводника. Зарегистрировано уменьшение времени жизни возбужденного состояния молекул на 64 и 30% для красителей 1 и 2, соответственно. Тушение времен жизни флуоресценции адсорбированных молекул является результатом передачи электрона от красителя к полупроводнику. Измерения фотовольтаических параметров солнечных ячеек, сенсибилизованных исследуемыми красителями показали большую эффективность для функционализированного красителя, что связано с более лучшей адсорбцией данного соединения на TiO2.
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