FEATURES OF STIMULATED EMISSION OF A MEROCYANINE DYE IN THE PORES OF ANODIZED ALUMINUM
DOI:
https://doi.org/10.31489/2021No2/29-34Keywords:
porous aluminum oxide, electrochemical anodizing, merocyanine dye, stimulated emission, polymethyl methacrylate.Abstract
The results of the study of the spectral-luminescent properties and the generation of stimulated emission of merocyanine dye molecules in a porous aluminum oxide films are presented. The addition of silver nanoparticles to the porous aluminum oxide films leads to an increase in the absorption cross section and an increase in the quantum yield of dye fluorescence in the alumina films. However, in the alumina films with silver nanoparticles, the generation of stimulated emission of dye molecules was not detected. We also studied the effect of polymethyl methacrylate polymer deposited on the surface of the alumina films with a dye on the spectral-luminescent properties and generation of stimulated emission of this dye. An increase in the optical density in the absorption band of the dye and an increase in the fluorescence intensity in samples with a deposited polymethyl methacrylate film are observed. The generation threshold of polymethine dye is reduced by a factor of 40 in the porous aluminum oxide sample with polymethyl methacrylate.
References
"1 Diggle J.W., Downie T.C., Coulding C. W. Printing on Anodized Aluminium Surface. Chemical Reviews. 1969, Vol. 69, pp. 365 – 405.
Shelkovnikov V.V., et al. Lasing of a solid-state active element based on anodized aluminum oxide film doped with rhodamine 6G. Russian Physics Journal. 2017, Vol. 59, No. 12, рр. 1989 – 1995.
Ibrayev N.Kh., Aimukhanov A.K. Influence of plasmon resonance in silver nanoparticles on the properties of stimulated emission of 1, 3, 5, 7, 8 - pentamethyl - 2,6-diethylpyrromethene difluoroborate molecules in film of porous aluminum oxide. Optics and Laser Technology. 2019, Vol. 115, рр. 246 – 250.
Afanasyev D.A., Ibrayev N.Kh., Omarova G.S., et al. Spectral-Luminescence and Lasing Properties of Merocyanine Dye Solutions in the Presence of Silver Nanoparticles. Optics and Spectroscopy. 2020, Vol. 128, No.1, рр.61 – 65.
Napolskii K.S., Barczuk P.J., Vassiliev S.Yu., et al. Templating of electrodeposited platinum group metals as a tool to control catalytic activity. Electrochimica Acta. 2007, Vol. 52, No. 28, рр. 7910 – 7919.
Aimukhanov A.K., Ibrayev N. Kh. Influence of gold nanoparticles on the properties of stimulated emission of 6-amino-1h-phenalen-1-one in the pores of anodized aluminum oxide. Journal of Luminescence. 2018, Vol. 204, рр.216 – 220.
Kulinich A.V., Derevyanko N.A., Ishchenko A.A., et al. Synthesis and spectral properties of malononitrile-based merocyanine dyes. Russian Chemical Bulletin. 2019, Vol. 54, No. 12, рр. 2820 – 2830
Bondarev S.L., et al. Fluorescence and solvatochromism of a merocyanine dye with a high quadratic polarizability in solutions and polymer films. Journal of Luminescence. 2007, Vol. 124, No. 1, рp.178 – 186.
Yang M., Moroz P., Jin Z., et al. Delayed photoluminescence in metal-conjugated fluorophores. JACS. 2019, Vol. 141, No. 28, рр.11286 – 11297.
Ibrayev N.Kh., Ishchenko A.A., Afanasyev D.A., Zhumabay N.D. Active laser medium for near-infrared spectral range based on electron-unsymmetrical polymethine dye and silver nanoparticles. Applied Physics B: Lasers and Optics. 2019, Vol. 125, рр. 1 – 7.
Chibisov A.K., Zakharova G.V., Gorner H., et al. Photorelaxation Processes in Covalently Linked Indocarbocyanine and Thiacarbocyanine Dyes. Journal of Chemical Physics. 1995, Vol. 99, рр. 886 – 893.
Butrimovich O.V., Voropay E.S., Ksenofontova N.M. Study of the photostability of active media based on polymethine dyes. All-Union Meeting: Inverse Population and Lasing on Transitions in Atoms and Molecules, 1986, 52 р. [in Russian].
Omarova G.S., Afanasyev D.A., Ibrayev N. Kh. Generation of stimulated emission of electron-unsymmetrical polymethine dye in films of porous aluminum oxide doped with gold nanoparticles. Theoretical and Applied Science. 2019, Vol. 78, No. 10, рр. 351 – 358.
Peterson O.G., Snavely B.B. Stimulated emission from flashlamp-exsited organic dyes in polymethyl methacrylate. Applied Physics Letters. 1968, Vol. 12, рр. 238 – 240.
"