ELECTROPHYSICAL PROPERTIES OF NEW NANOSTRUCTURED COPPER-ZINC MANGANITE OF LANTHANUM AND MAGNESIUM

ELECTROPHYSICAL PROPERTIES OF NEW NANOSTRUCTURED COPPER-ZINC MANGANITE OF LANTHANUM AND MAGNESIUM

Authors

DOI:

https://doi.org/10.31489/2022No2/42-47

Keywords:

copper-zinc manganite, lanthanum, magnesium, nanostructured particles, electron microscopy, X-ray, electrophysics, semiconductor

Abstract

The polycrystalline copper-zinc manganite was synthesized by the solid-phase interaction in the range of 800-1200 °C of oxides of lanthanum (III), copper (II), zinc (II), manganese (III) and magnesium carbonate, thus its nanostructured particles were first obtained by grinding on the vibrating mill “Retsch” (Germany). The X-ray investigations determined that the nanostructured manganite is crystallized in the cubic syngony. On the LCR7817/827 device (Company «Good Will Instrument Co., Ltd., Taiwan») in the range of 293-483 K at frequencies equal to 1.5 and 10 kHz, the dielectric constant and electrical resistance were investigated and it was found that this compound at 293-353 K has the semiconductor conductivity, at 353-373 K - metal and at 373-483 K - semiconductor conductivity again. The band gap widths were calculated. The permittivity at 483 K reaches gigantic values at all frequencies. Referring to the above, the objective of this paper is to study the temperature dependence of the dielectric constant and the electrical resistance of a new nanostructured copper-zinc manganite of lanthanum and magnesium.

Author's detail

Bulat Kasenov, Abishev Chemical-Metallurgical Institute

Doctor of chem. sciences, Professor, Head of the Laboratory of Thermochemical Processes, Abishev Chemical-Metallurgical Institute, Karaganda, Kazakhstan, ORCID ID: 0000-0001-9394-0592, kasenov1946@mail.ru

Shuga Kasenova, Abishev Chemical-Metallurgical Institute

Doctor of chem. sciences, Professor, Chief researcher, Laboratory of Thermochemical Processes, Abishev Chemical-Metallurgical Institute, Karaganda, Kazakhstan; ORCID ID: 0000-0001-9755-7478, kasenovashuga@mail.ru

Zhenisgul Sagintaeva, Abishev Chemical-Metallurgical Institute

Candidate of chem. sciences, Associate Professor, Leading Researcher, Laboratory of Thermochemical Processes, Abishev Chemical-Metallurgical Institute, Karaganda, Kazakhstan; ORCID ID: 0000-0001-8655-356, kai_sagintaeva@mail.ru

Erbolat Kuanyshbekov, Abishev Chemical-Metallurgical Institute

Master (Eng.), Leading Engineer, Laboratory of Thermochemical Processes, Abishev Chemical-Metallurgical Institute, Karaganda, Kazakhstan; ORCID ID: 0000-0001-9172-9566; mr.ero1986@mail.ru

Zhanaly Bekturganov, E.A. Buketov Karaganda University

Doctor of chem. sciences, Professor, Department of radiophysics and electronics, E.A. Buketov Karaganda University, Karaganda, Kazakhstan, zhbekturganov@gmail.com 

Asylbek Zeynidenov, E.A. Buketov Karaganda University

PhD, Associate professor, Dean of the Physical-Technical Faculty, Scientific Center for Nanotechnology and Functional Nanomaterials, E.A. Buketov Karaganda University, Karaganda, Kazakhstan; ORCID ID: 0000-0001-9780-5072, Scopus Author ID: 56386144000, asyl-zeinidenov@mail.ru

References

Tretyakov Yu.D., Brylyov O.A. New generations of inorganic functional materials. Journal of the Russian Chemical Society named after D.I. Mendeleev, 2000, Vol. 44, No. 4, pp. 10-16. [in Russian].

Kasenov B.K., Kasenova Sh.B., Sagintaeva Zh.I., Ermagambet B.T., Bekturganov N.S., Oskembekov I.M. Double and triple manganites, ferrites and chromites of alkali, alkaline earth and rare earth metals. Moscow, Nauchnyi mir, 2017, 416 p. [in Russian].

Solin N.I., Naumov S.V. Magnetic and electrical properties of weakly doped manganese-deficient La1xCaxMn1zO3 manganites. Journal of Experimental and Theoretical Physics, 2013, Vol. 116, No. 1, pp. 145-158. https://doi.org/10.1134/s1063776113010172

Golenishchev-Kutuzov A.V., Golenishchev-Kutuzov V.A., Ismagilov I.R., etc. Magnetically controlled structural, Yang-Teller, dielectric, and transport effects La0,875Sr0.125MnO3. Izvestiya RAS. Physics Series, 2015, Vol. 79, No. 6, pp. 768-770 [in Russian].

Erin Yu. Substance with high value of dielectric capacitivity was found. Chemistry and Chemists, Part 1, 2009. Available at the: http://chemistry-chemists.com/N1_2009/16-22.pdf [in Russian].

Aksenova T.V., Gavrilova L.Ya, Cherepanov V.A. Crystal structure and physicochemical properties of doped lanthanum manganites. Russian Journal of Physical Chemistry A, 2012, Vol. 86, pp. 1862-1868. https://doi.org/10.1134/S0036024412120023

Ivanov A.I., Agarkov D.A., Burmistrov I.N., Kudrenko E.A., Bredikhin S.I., Kharton V.V. Synthesis and Properties of Fuel Cell Anodes Based on (La0,5+xSr0,5–x)1–yMn0,5Ti0,5O3–δ (x = 0-0.25, y = 0-0.03). Russian Journal of Electrochemistry, 2014, Vol. 50, No 8, pp. 730-736. https://doi.org/10.1134/S1023193514080047

Kasenova Sh.B., Sagintaeva Zh.I., Kasenov B.K., Turtubaeva M.O., Nukhuly A., Kuanyshbekov Ye.Ye., Issabaeva M.A. New nanostructured manganites of LaMeIICuZnMnO6 (MeII – Mg, Ca, Sr, Ba). Bulletin of the Karaganda University. Chemistry Series, 2021, Vol. 103, No. 3, pp. 60-66. https://doi.org/10.31489/2021ch3/60-66

Kovba L.M., Trunov V.K. X-ray phase analysis. Moscow, 1976, 256 p. [in Russian].

Kivilis S.S. Technique of measuring of the density of liquids and solids. Moscow, 1959, 191 p. [in Russian].

Kasenov B.K., Kasenova Sh.B., Sagintaeva Zh.I., Nukhuly A., Turtubaeva M.O., Bekturganov Zh. S., Zeinidenov A.K., Kuanyshbekov E.E., Issabaeva M.A. Synthesis and X-ray investigation of novel nanostructured copper-zinc manganites of Lanthanum and alkali metals. Eurasian Physical Technical Journal, 2021, Vol. 18, No. 1, pp. 29-33. https://doi.org/10.31489/2021no1/29-33

Okadzaki K. Technology of ceramic materials. Moscow, 1976, 256 p. [in Russian].

Fesenko E.G. Perovskite family and ferroelectricity. Moscow, 1972, 248 p. [in Russian].

Venevcev Yu.N., Politova E.D., Ivanov S.A. Ferroelectric and antisegnetoelectrics of the barium titanate family. Moscow, 1985, 256 p. [in Russian].

Kassenova Sh.B., Sagintayeva Zh.I., Kassenov B.K., Kuanyshbekov E.E, Bekturganov Zh.S., Zeinidenov A.K. Electrophysical characteristics of nanodimensional cobalte-cuprate-manganite LaNa2CoCuMnO6 and nickelite-cuprate-manganite LaNa2NiCuMnO6. Bulletin of the Karaganda University. Physics Series, 2020, Vol. 98, No. 2, pp. 43-49. https://doi.org/10.31489/2020ph2/43-49

Tretyakov Yu.D. Problem of development of nanotechnology in Russia and abroad. Bulletin of the Russian Academy of Sciences, 2007, Vol. 77, No 1, pp. 3-10. [in Russian].

Barfoot J. Introduction to the physics of ferroelectric phenomena. Moscow, 1970, 352 p. [in Russian].

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How to Cite

Kasenov, B., Kasenova, S., Sagintaeva, Z., Kuanyshbekov, E., Bekturganov, Z., & Zeynidenov, A. (2022). ELECTROPHYSICAL PROPERTIES OF NEW NANOSTRUCTURED COPPER-ZINC MANGANITE OF LANTHANUM AND MAGNESIUM. Eurasian Physical Technical Journal, 19(2(40), 42–47. https://doi.org/10.31489/2022No2/42-47

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