Impact research of electron beam processing on the structure and properties of РА6 polyamide

Impact research of electron beam processing on the structure and properties of РА6 polyamide

Authors

DOI:

https://doi.org/10.31489/2019No2/43-47

Keywords:

electron irradiation, polyamide, wear resistance, hardness, structure

Abstract

In this work we studied the impact of electron irradiation with energy of 1.3 MeV on the structure and properties of PA6 polyamide. Irradiation doses ranged from 50 to 500 kGy. The results of research presented that irradiation with small doses of PA6 polymer is able to increase the mechanical characteristics, while irradiation with large doses significantly reduces them. Wear resistance decreases under irradiation conditions from 350 kGy, and the hardness of the samples varies slightly. The polymer structure was studied by X-ray diffractometry and IR spectroscopy. Electron irradiation at an energy of 1.3 MeV did not lead to a change in the crystalline form of the PA6 polymer, but caused partial crystalline damage. The peak intensity of the α-phase after electron irradiation increases compared with the unirradiated sample. It may be due to an increase in the crystallinity of the polymer.

References

"1 Raghu S., Archana K., Sharanappa C., Ganesh S., Devendrappa H. The physical and chemical properties of gamma ray irradiated polymer electrolyte films. Journal of Non-Crystalline Solids. 2015, Vol.426, pp.55 – 62.

Pikaev A.K. Novye razrabotki radiatsionnoi tehnologii v Rossii. Himia vysokih energii, 1999, Vol.32, pp. 3 – 11. [in Russian].

Sarada I., Ahmad A., Bakar A., et al. Influence of gamma irradiation on polymerization of pyrrole and glucose oxidase immobilization onto poly (pyrrole)/poly(vinyl alchohol) matrix. Applied Surface Science, 2017, Vol.400, pp. 118-128.

Visco A.M., Torrisi L., Campo N., et al. Mechanical Performance of Electron-Beam-Irradiated UHMWPE in Vacuum and in Air. J Biomed Mater Res Part B: Appl. Biomater, 2009, 89B, pp. 55 – 64.

Slouf M., Synkova H., Baldrian J., Marek A., et al. Structural changes of UHMWPE after e-beam irradiation and thermal treatment. J Biomed Mater Res Part B: Appl.Biomater, 2008, 85B, pp.240 – 251.

Shifeng Zhu, Meiwu Shi, Meifang Zhu Effects of Electron-Beam Irradiation Crosslinking on PA6 Fibers. Fibers and Polymers, 2013, Vol.14, No.4, pp.525 – 529.

Shifeng Zhu, Meiwu Shi, Meifang Zhu. Effects of Electron-Beam Irradiation Crosslinking on PA6 Fibers. Fibers and Polymers. 2013, Vol.14, No.4, pp.525 – 529.

Nalwa H.S. Ferroelectric Polymers. Marcel Dekker, New York, 1995, pp.283 – 286.

SibiliaJ.P.A Guide to Material Characterization and Chemical Analysis. VCH Publishers, New York, 1996, pp.148 – 150.

Sengupta R., Bandyopadhyay A., Sabharwal S., Chaki T.K. Polyamide-6,6/in situ silica hybrid nanocomposites by sol-gel technique: synthesis, characterization and properties. Polymer, 2005, Vol.46, No.10, pp.3343 – 3354.

Makuuchi K., Cheng S. Radiation Processing of Polymer Materials and Its Industrial Applications, John Wiley & Sons, Inc., New Jersey (2012).

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How to Cite

Rakhadilov, B., Sagdoldina, Z., Ocheredko, I., Kombaev, K., & Khassenov, A. (2019). Impact research of electron beam processing on the structure and properties of РА6 polyamide. Eurasian Physical Technical Journal, 16(2(32), 43–47. https://doi.org/10.31489/2019No2/43-47

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Section

Materials science

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