Synthesis and X-ray investigation of novel nanostructured copper-zinc manganites of lanthanum and alkali metals

Synthesis and X-ray investigation of novel nanostructured copper-zinc manganites of lanthanum and alkali metals

Authors

DOI:

https://doi.org/10.31489/2021No1/29-33

Keywords:

copper-zinc manganite, lanthanum, alkali metals, synthesis, nanostructured particles of X-ray phase analysis.

Abstract

"The aim of this work is to synthesize new nanostructured copper-zinc lanthanum and alkaline metal manganites. Polycrystalline copper-zinc manganites of lanthanum and alkali metalswere synthesizedby the method of ceramic technology from lanthanum (III), copper (II), zinc (II), manganese (III) oxides, and lithium, sodium, and potassium carbonates in the range of 800-1200 oC. Nanostructured particles were obtained by grinding the synthesized polycrystalline compounds at the «MM301» vibration mill of «Retsch» (Germany). By indexing X-ray images of nanostructured copper-zinc lanthanum and alkaline metal manganites, it was found that they crystallize in cubic syngony. Their lattice parameters are determined. There is a pattern in the change of the lattice parameters from the ionic radii of alkaline metals. "

References

"1 TretyakovYu.D.,Brylyov O.A. New generations of inorganic functional materials. Journal of the Russian Chemical Society named after D.I. Mendeleev,2000, Vol. 44, No. 4, pp. 10-16. [in Russian].

Grunberg P.A. From spin waves to giant magnetoresistance and beyond. Physics-Uspekhi, 2008,Vol. 178, Iss. 12, pp. 1349-1358. DOI: 10.3367/ufnr.0178.200812g.1349. [in Russian].

Erin Yu. Substance with high value of dielectric capacitivity was found. Chemistry and Chemists, Part 1, 2009. Available at the: http://chemistry-chemists.com/N1_2009/16-22.pdf [in Russian].

Kuznetsov M.V., MorozovYu.G., Belousova O.V., Ortega D. Ferromagnetic nanoparticles of Zn/ZnO. Inorganic Materials, 2014,Vol. 50, No. 4, pp. 399-409. DOI: 10.7868/s0002337x14040101. [in Russian].

Solin N.I., Naumov S.V. Magnetic and electrical properties of weakly doped manganese-deficient La1xCaxMn1zO3manganites. Journal of Experimental and Theoretical Physics, 2013, Vol. 116, No. 1, pp. 145-158.

Nagaev E.L. Physics of magnetic semiconductors. Moscow, Nauka, 1983, 220 p. [in Russian].

Perekalina T.M., Sivokon T.A., Cherkezyan S.A. et al. Magnetic and electrical properties of La1-xSrxMnO3. Physics of the Solid State, 1989, Vol. 31, No. 9,pp. 87-89.[in Russian].

Kasenov B.K., Kasenova Sh.B., Sagintaeva Zh.I., et al. Double and triple manganites, ferrites and chromites of alkali, alkaline earth and rare earth metals. Moscow, 2017, 416 p.[in Russian].

Kasenov B.K., Kasenova, Sh.B., Sagintaeva, Zh.I., et al. Physical properties of manganites. Karaganda, 2017, 123 p.

Kasenov B.K., Kasenova, Sh.B., Sagintaeva Zh.I., Kuanyshbekov E.E.New materials based on oxides of s-, d- and f-elements. Karaganda, 2017, 117 p. [in Russian].

Ermaganbetov K.T., ChirkovaL.V., KasenovB.K. Physics of magnetic and kinetic phenomena in manganites of lanthanides. Karaganda, 2017, 251 p.

Kasenov B.K., Kasenova Sh.B., Sagintaeva Zh.I., et al. New substituted polycrystalline and nanodimensional manganites. Karaganda, Ecozhan, 2019, 108 p.[in Russian].

Baisanov S.O., Gabdulin G.G., Takenov T.D. About organization of production of manganese ferroalloy from Kazakhstan raw materials. Steel,1997, Vol. 7, pp. 29-32. [in Russian].

Baisanov S.O., Takenov T.D., Tolymbekov M.Zh. About conditions of selective reduction in the Fe−Mn−O system]. Bulletin of the Karaganda University. Chemistry series,2005, No. 4(40), pp. 65-70. [in Russian].

KassenovaSh.B., SagintayevaZh.I., Kassenov B.K., Kuanyshbekov E.E, BekturganovZh.S., Zeinidenov A.K. Electrophysical characteristics of nanodimensionalcobalte-cuprate-manganite LaNa2CoCuMnO6 and nickelite-cuprate-manganite LaNa2NiCuMnO6. Bulletin of the Karaganda University. Physics Series, 2020. No. 2(98), pp.43-49.

Kovba L.M., Trunov V.K. X-ray phase analysis. Moscow, 1976, 256 p.[in Russian].

Kivilis S.S. Technique of measuring of the density of liquids and solids. Moscow, 1959,191 p. [in Russian].

Tretyakov Yu.D. Challenges of nanotechnological development in Russia and abroad. Herald of the Russian Academy of Sciences, 2007, Vol. 77, No.1, pp. 15-21.DOI: 10.1134/s1019331607010030.

Vest A. Chemistry of solid state. Moscow, World, 1988, 588 p. [in Russian].

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How to Cite

Kasenov, B., Kasenova, S., Sagintaeva, Z., Nukhuly, A., Turtubaeva, M., Bekturganov, Z., Zeinidenov, A., Kuanyshbekov, E., & Issabaeva, M. (2021). Synthesis and X-ray investigation of novel nanostructured copper-zinc manganites of lanthanum and alkali metals. Eurasian Physical Technical Journal, 18(1(35), 29–33. https://doi.org/10.31489/2021No1/29-33

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Materials science
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