ELECTRICAL CHARACTERISTICS OF SEMICONDUCTOR POLYMER FILMS DOPED WITH SILVER NANOPARTICLES
Keywords:
semiconductor polymer, silver nanoparticles, polymer solar cell, core – shell nanostructureAbstract
The electrical properties of composite films based on polymer PEDOT:PSS with а addition of Ag nanoparticles or Ag–TiO2 nanostructures have been studied. A current–voltage characteristic is observed for polymer solar cells. A short circuit current increased after adding of Ag nanoparticles or Ag–TiO2 nanostructures to the PEDOT:PSS polymer. Also, an increase in the recombination rate in cells with silver nanoparticles is observed. An electrical impedance is measured for polymer solar cells. A significant increase in the dielectric constant of a PEDOT:PSS film containing silver nanoparticles was detected.
References
"1 Pavlov N. What Barriers Will Overcome Printed Solar Elements. Vector of High Technologies. 2013, No.3 (3), pp. 8 – 14. [in Russian]
Chan K., Wright M., Elumalai N. Uddin A., Pillai S. Plasmonics in Organic and Perovskite Solar Cells: Optical and Electrical Effects Adv. Optical Mater. 2017, Vol. 5, No.6. pp. 1600698(1-19).
Pillai S., Catchpole K.R., Trupke Т., Green M. J. Surface plasmon enhanced silicon solar cells Appl. Phys. 2007, Vol.101, No.9, pp. 093105(1) - 093105(8).
Schaadt D.M., Feng В., Yu E.T. Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles Appl. Phys. Lett. 2005, Vol. 86, No.6, pp. 063106(1-3).
Ikhsanov Sh., Protsenko I.E., Uskov A.V. Increasing the efficiency of organic solar cells using plasmonic nanoparticles Tech. Phys. Letters. 2013, Vol.39, No.5, pp. 450 – 453.
http://www.nrel.gov/ncpv/images/efficiency_chart.jpg
Kukhta A.V., Pochtenny A.E., Misevich A.V. et. al. Optical and electrophysical properties of nanocomposites based on PEDOT: PSS and gold/silver nanoparticles Phys. of the Sol. St. 2014, Vol. 56, No.4, pp. 827 – 834.
Lee C.S., Kima J.Y., Lee D.E. et. al. Flexible and transparent organic film speaker by using highly conducting PEDOT/PSS as electrode Synthetic Metals. 2003, Vol.139, pp. 457–461.
Wang G.-F., Tao X.-M., Xin J.H., Fei B. Modification of conductive polymer for polymeric anodes of flexible organic light-emitting diodes Nanoscale Res. Lett. 2009, No.4, pp. 613 – 617.
Afanasyev D.A., Ibraev N.Kh. Increasing the conductivity of composite semiconductor polymer films based on Pedot: PSS Solid State Physics, Functional Materials and New Technologies (FTT-2018): Materials of the XIV International Scientific Conference. Bishkek- Karaganda, 2018, pp. 11 – 13. [in Kazakh]
Stratakis E., Kymakis E. Nanoparticle-based plasmonic organic photovoltaic devices. Materials Today. 2013, Vol.16, Issue 4, pp. 133 – 146.
Afanasyev D.A., Ibrayev N.Kh., Serikov T.M., Zeinidenov A.K. Effect of the titanium dioxide shell on the plasmon properties of silver nanoparticles Russian Journal of Physical Chemistry A. 2016, Vol. 90, No.4, pp. 833 – 837.
Afanasyev D.A., Ibraev N.Kh. The Effect of Ag-TiO2 Nanostructures on Photoprocesses in Poly [3-Hexylthiophene] Polymer Mat. Res. Scientific-Practical Conference. Karaganda, 2018, pp. 148–151. [in Kazakh]
Ibrayev N.Kh., Afanasyev D.A., Zhapabaev K.A. Effect of potassium iodide on luminescent and photovoltaic properties of organic solar cells P3HT-PCBM IOP Conf. Series: Mat. Sc. and Eng. 2016, Vol.110, pp. 012067 (1-5).
Ibrayev N.Kh., Nurmakhanova A., Afanasyev D. Role of spin states in the process of electron en-ergy transformation in P3HT films, doped KI salt IOP Conf. Series: Materials Science and Engineering. 2017, Vol.168, pp. 012060.
Knipper M., Parisi J., Coakley K. et al. Impedance Spectroscopy on Polymer-Fullerene Solar Cells Zeitschrift für Naturforschung A. 2007, Vol. 62, No 9, pp. 490 – 494.
Aleksandrova M., Kolev G.I. et. al. Characterization of Piezoelectric Microgenerator with Nanobranched ZnO Grown on a Polymer Coated Flexible Substrate Appl. Sc. 2017, Vol. 7(9), pp. 1 – 11.
Ghanipourand M., Dorranian D. Effect of Ag-Nanoparticles Doped in Polyvinyl Alcohol on the Structural and Optical Properties of PVA Films J. of Nanomat. 2013, Vol. 2. pp. 1 – 10.
N. Kalfagiannis, P. G. Karagiannidis, et. al. Plasmonic silver nanoparticles for improved organic solar cells Sol. Energy Mater. Sol. C. 2012, Vol. 104, pp.165–174.
G. Garcia-Belmonte, A. Munar, E.M. Barea, J. Bisquert, I. Ugarte, R. Pacios Charge carrier mobility and lifetime of organic bulk heterojunctions analyzed by impedance spectroscopy Organic Electronics. 2008, Vol. 9(5), pp. 847 – 851.
"