Сирекжер және ауыспалы металдардың оксидтері негізіндегі жаңа жартылай өткізгіштің термодинамикалық және электрфизикалық қасиеттері
DOI:
https://doi.org/10.31489/2025N3/36-47Кілт сөздер:
манганит, лантан, цирконий, натрий, жылусыйымдылық, термодинамикалық функциялар, электрофизикаАңдатпа
Зерттеу жұмысы манганиттер мен цирконаттардың қасиеттерін біріктіретін жаңа қосылысты зерттеуге арналған, бұл жоғары тиімді функционалды материалдарды жасауға жол ашады. Қосылыс лантан оксиді, цирконий оксиді, марганец оксиді және натрий карбонатының 800–1200 °C температура аралығындағы әрекеттесуі арқылы синтезделіп, рентгенқұрылымдық талдау әдістерімен, соның ішінде кубтық тор параметрлерін анықтау арқылы зерттелді. Жылусыйымдылықтың температураға тәуелділігін талдау екінші ретті фазалық ауысуларды көрсетті және оның өзгерісін сипаттайтын теңдеулер шығарылды. Энтропия мен энтальпия сияқты термодинамикалық сипаттамалар есептелді. Электрофизикалық өлшеулер белгілі бір температура диапазонында материалдың жартылай өткізгіштік табиғатын растады және эталондық материалдардан асып түсетін диэлектрлік өтімділіктің жоғары мәндерін көрсетті.
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